Unable to view TOC on the navigation Pane - Microsoft Community
https://answers.microsoft.com/en-us/msoffice/forum/all/unable-to-view-toc-on-the-navigation-pane/dbbaed0a-b292-4847-bcec-4aa70d9d1955
You can add the TOC's heading to the Navigation pane as follows: Click in the Table of Contents heading and press Ctrl+Shift+S to open the Apply Style dialog. ... Click the Modify button in the dialog. In the Modify Style dialog, click "New documents based on this template" and click Format > Paragraph. In the Paragraph dialog, click the Outline Level dropdown and choose Level 1. OK all dialogs.
Click in the Table of Contents heading and press Ctrl+Shift+S to open the Apply Style dialog. ...
Click the Modify button in the dialog.
In the Modify Style dialog, click "New documents based on this template" and click Format > Paragraph.
In the Paragraph dialog, click the Outline Level dropdown and choose Level 1.
OK all dialogs.
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